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给出了包含宏观应变和微形变的全部二次项以及宏观应变三次项的一种新的自由能函数.利用新自由能函数并根据Mindlin微结构理论,建立了描述微结构固体中纵波传播的一种新模型.利用近来发展的奇行波系统的动力系统理论,分析了系统的所有相图分支,并给出了周期波解、孤立波解、准孤立尖波解、孤立尖波解以及紧孤立波解.孤立尖波解和紧孤立波解的得到,有效地证明了在一定条件下,微结构固体中可以形成和存在孤立尖波和紧孤立波等非光滑孤立波.此结果进一步推广了微结构固体中只存在光滑孤立波的已有结论. 相似文献
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In this paper, we summarize the existing methods of solving the evolution equation of the leading-twist \begin{document}$B$\end{document} ![]()
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-meson LCDA. Then, in the Mellin space, we derive a factorization formula with next-to-leading-logarithmic (NLL) resummation for the form factors \begin{document}$F_{A,V}$\end{document} ![]()
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in the \begin{document}$B \to \gamma \ell\nu$\end{document} ![]()
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decay at leading power in \begin{document}$\Lambda/m_b$\end{document} ![]()
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. Furthermore, we investigate the power suppressed local contributions, factorizable non-local contributions (which are suppressed by \begin{document}$1/E_\gamma$\end{document} ![]()
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and \begin{document}$1/m_b$\end{document} ![]()
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), and soft contributions to the form factors. In the numerical analysis, which employs the two-loop-level hard function and the jet function, we find that both the resummation effect and the power corrections can sizably decrease the form factors. Finally, the integrated branching ratios are also calculated for comparison with future experimental data. 相似文献
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《Arabian Journal of Chemistry》2020,13(3):4564-4576
Versatile graphdiyne (GDY) substrate has been modified by numerous transition metals and resulting composites showed excellent photo/electro-catalytic performance. However, GDY materials modified by actinides that are stockpiled waste product due to large-scale use in nuclear industry, are particularly scarce and remains great challenge. To deeply understand the structural properties, GDY complexating actinyl (AnmO2)n+ (An = U, Np, Pu; m = VI, V) species with its atomistic pore was investigated by relativistic density functional theory (DFT). The GDY pore was found suitable to hold actinyl species, by forming organometallic AnC dative bonds. This chemical coupling interaction was further confirmed by quantum theory of atoms-in-molecule and electronic structure calculations. The GDY-uranyl(V), for instance, shows a π(UC) bonding HOMO, which is anticipated to improve electron transfer between ligand and metal. Orbital structures and compositions of complexes suggest their implication towards catalysis, which were further corroborated by calculations on redox potentials of GDY-actinyl complexes. Hence, our results show the potential applications of GDY complexating actinyl species towards novel catalytic surfaces. 相似文献
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Lu Chen Nan Tu Qianyang Wei Tao Liu Chengzhi Li Wenbo Wang Jianhui Li Hailin Lu 《Surface and interface analysis : SIA》2022,54(3):218-230
In this paper, graphene oxide/polyethylene glycol (GO/PEG) composite water-based lubricant was prepared by an ultrasonic dispersion method, and characterized and analyzed by Fourier transform infrared (FT-IR), Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The suspension performance of GO/PEG composite water-based lubricant in water was verified by static sedimentation and centrifugation, and then, the prepared GO/PEG composite water-based lubricant was added into 304 stainless steel and 6061 aluminum alloy, and the coefficient of friction (COF) curve, average COF value, average wear rate, corresponding photomicrographs of balls and disks after wear, and energy-dispersive spectrometer (EDS) elemental analysis were used to illustrate the lubrication effect and lubrication mechanism. The results show that the GO/PEG composite water-based lubricant possesses excellent suspension ability in water, and the average COF value and wear rate of GO/PEG composite water-based lubricant are reduced by 78.8% and 88.8%, respectively, compared with water lubrication. The excellent lubrication effect of GO/PEG composite water-based lubricant can effectively reduce the cold-welding and adhesive wear phenomenon, mainly because GO/PEG composite water-based lubricant first fills the uneven surface of friction mating to form a high-quality lubricating film and then because of the special space structure of GO and the low shear between GO layers and the synergistic lubrication effect of GO/PEG. 相似文献
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Research on Chemical Intermediates - The structure and racemization mechanism of l-aspartic acid (l-ASP) and l-ASP-intercalated layered double hydroxide (l-ASP-LDH, with intercalated... 相似文献
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The aim of this work is to overview the specific effect of pH buffers in biological systems. The pH of a buffer solution changes only slightly when a small amount of a strong acid or bases is added to it. This is widely accepted and applied both in chemical and in biological (i.e. enzyme catalysis) systems. Here we show some examples – spanning from pH measurements, enzyme activities, electrophoretic mobilities, antibody aggregation, protein thermal stability – that demonstrate additional roles of buffers. They not only set pH, but also address specific ion effects, in terms of Hofmeister series, when strong electrolytes are also added. From the experimental data referred to some charged biological moieties it emerges that different buffers, at the same nominal pH, can specifically adsorb at the charged surface. Buffer specific adsorption modifies several molecular and macroscopic properties amongst which electrophoretic mobilities, and hence effective surface charges, are particularly significant. More importantly, buffers' weak electrolytes, even at low concentration, are found to compete for the adsorption at the charged surfaces with strong electrolytes, thus modulating Hofmeister effects. 相似文献